Hydrochloric acid, #"HCl"#, and potassium hydroxide, #"KOH"#, react in a #1:1# mole ratio to produce aqueous potassium chloride, #"KCl"#, and water.
This means that a complete neutralization requires equal numbers of moles of hydrochloric acid, i.e. of hydronium cations, #"H"_3"O"^(+)#, and of potassium hydroxide, i.e. of hydroxide anions, #"OH"^(-)#. As you know,m molarity is defined as the number of moles of solute present in #"1 L"# of solution. Now, notice that the potassium hydroxide solution, which has a molarity of #"0.350 M"#, is
times more concentrated than the hydrochloric acid solution, which has a molarity of #"0.100 M"#. In other words, for the same volume of both solutions, the potassium hydroxide solution contains #color(red)(3.5)# times more moles of solute than the hydrochloric acid solution. This means that in order to have equal numbers of moles of both solutes, you need to have a volume of hydrochloric acid solution that is #color(red)(3.5)# times bigger than the volume of the sodium hydroixde solution. Since the sodium hydroixde solution has a volume of #"50.0 mL"#, it follows that the volume of hydrochloric acid needed will be
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